Lecture 10

Standard molar Gibbs energies; Criteria of Reversibility; Combining 1st and 2nd Laws of Thermodynamics; Partial molal free energy; Chemical Potential; Effect of T and P on G; Gibbs-Helmholtz equation; Kinetic controlled reactions; Interpretation of Gibb’s equation; Phase equilibria in pure substances; Clapeyron’s equation; Trouton's rule; Richard's rule; Dependence of free energy change on activity; Meaning of spontaneity; Equilibrium & Conventional constants; Effect of T, P & inert gas on K; Absolute Entropy; Third Law of Thermodynamics; Debye’s Law of third power.

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