The current review article represents a survey covering the literatures on azoles, azines and azepines fused to the a face of a benzimidazole moiety since 1980. Synthetic routes leading to benzimidazole fused with different ring systems; five-, six-, and seven-membered heterocyclic rings, containing one-, two- and three-heteroatoms were reported utilizing simple reactive benzimidazole synthons.
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