Safwat, S. M., M. Medhat, and H. A. El-Halim,
"Adsorption of phenol onto aluminium oxide and zinc oxide: A comparative study with titanium dioxide",
Separation Science and Technology: Taylor & Francis, pp. 1-13, 2018.
AbstractThis study conducted an investigation of aluminium oxide’s and zinc oxide’s ability to remove phenol from wastewater through adsorption, and compare of their performance with titanium dioxide. The points of zero charge for the adsorbents were determined. The highest removal efficiencies for aluminium oxide, zinc oxide, and titanium dioxide were 14.7%, 12.2% and 33.5%, respectively. Equilibrium studies demonstrated the possibility of Frendluich isotherm, Temkin isotherm, and Dubinin–Radushkevich isotherm respectively expressing the adsorption isotherms for aluminium oxide, zinc oxide, and titanium dioxide. FTIR and SEM were used in conducting investigation on adsorbents. Among the three adsorbents, titanium dioxide was the best.
Safwat, S. M., and M. E. Matta,
"Adsorption of urea onto granular activated alumina: A comparative study with granular activated carbon",
Journal of Dispersion Science and Technology, vol. 39, issue 12: Taylor & Francis, pp. 1699-1709, 2018.
AbstractThis study investigated the ability of granular activated alumina to remove urea from wastewater through adsorption, and compared its performance with granular activated carbon. XRF, EDX, XRD, and TGA were used to investigate the adsorbents. The removal of urea as a function of pH value was studied. The point of zero charge for activated alumina was found to be 8.8, while that for activated carbon was found to be 7.1. The experimental data of the adsorption process were explored by fitting to different kinetic models to determine the adsorption kinetics and mechanisms. Then, the equilibrium data were examined by fitting to various two-parameter and three-parameter isotherm models. Results showed that the removal efficiency increased with the increasing pH value. The maximum removal efficiencies were 24% and 31% for granular activated alumina and granular activated carbon, respectively, at pH = 9.0. Kinetic studies showed that adsorption of urea onto both activated alumina and activated carbon can be expressed by pseudo second order kinetics. Equilibrium studies showed that the adsorption isotherms could be expressed by the Redlich-Peterson isotherm and Temkin isotherm for activated alumina and activated carbon, respectively. Adsorbents were investigated using FTIR and SEM, and results showed the occurrence of adsorption.