Copolymerization and interaction of acrylonitrile and indene

Citation:
Mikhael, M. G., S. M. Mokhtar, G. R. Saad, M. M. Naoum, and M. Z. Elsabee, "Copolymerization and interaction of acrylonitrile and indene", Journal of Polymer Science Part A: Polymer Chemistry, vol. 27, issue 1, pp. 185 - 191, 1989.

Abstract:

The donor–acceptor interaction of acrylonitrile (AN) with indene (In) has been investigated by means of ultraviolet spectroscopy and dielectric polarization measurements. The latter method yielded a value of 0.5 for the association constant of the charge‐transfer‐complex (CTC) and a 4.02 D for its dipole moment. The copolymerization of the two monomers was characterized by a tendency towards alternation when conducted in the bulk. This might be due to the participation of a weak CTC in the process of copolymerization. However, this tendency disappeared in polar solvents such as DMF. Copyright © 1989 John Wiley & Sons, Inc.

Notes:

Cited By :5Export Date: 6 March 2019

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