In this work, we report a single-step preparation of porous Ni-based thin layer foams atop a Cu substrate via the facile dynamic hydrogen bubble template (DHBT) technique. As-prepared porous Ni-based foams were characterized by various electrochemical measurements, namely, scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS).